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81.
82.
Yejun Wu Bowen Yan Juan Zhou Huizhang Lian Xiaojun Yu Jianxin Zhao Hao Zhang Wei Chen Daming Fan 《Journal of food science》2020,85(10):3282-3292
83.
《Ceramics International》2020,46(9):13125-13132
It is of great significance to develop highly active and cost-effective electrocatalysts for the oxygen evolution reaction and hydrogen evolution reaction in alkaline solution. Herein, we report an interface engineering strategy to fabricate 3D hierarchical CuCo2O4@CuCo2S4 heterostructure catalysts with efficient synergistic effects for water splitting. Owing to the special nano-architectures with abundant active interfaces, the as-prepared CuCo2O4@CuCo2S4 catalysts exhibit superior electrochemical activity and prominent electrochemical stability, with a small overpotential of 240 and 101 mV for oxygen and hydrogen evolution reactions to deliver a current density of 10 mA cm−2, respectively. Remarkably, the CuCo2O4@CuCo2S4 materials directly applied as both anode and cathode electrode demonstrate excellent water splitting performance, achieving 10 mA cm−2 at a low cell voltage of only 1.53 V, outperforming the integrated state-of-the-art RuO2||Pt/C couple (1.56 V). Moreover, density functional theory calculations suggest that the excellent overall water splitting property of CuCo2O4@CuCo2S4 is attributed to a large amount of hierarchical hetero-interfaces, giving rise to effective adsorption and cleavage of H2O molecules on the catalyst surface. This work represents a general strategy to exploit efficient and stable hybrid electrocatalysts for renewable energy applications by rational catalyst interface engineering. 相似文献
84.
按照管道加工工艺的不同,管道可分为内径控制管和外径控制管。通过热轧工艺生产的外径控制无缝钢管,可满足火力发电厂汽水系统中绝大部分管道的使用要求。对于超(超)临界机组的主蒸汽和高温再热蒸汽管道采用的P91/P92材质的大口径厚壁无缝钢管,由于对材料性能和加工工艺有特殊要求,因此宜采用内径控制管。 相似文献
85.
Abrasive jet micro-machining (AJM) uses compressed air carrying abrasive solid particles to micro-machine a variety of features into surfaces. If the feature sizes are less than the size of the abrasive jet footprint, then a patterned erosion-resistant mask is used to protect the substrate material, leaving exposed areas to define the features. Previous investigations have revealed a ‘blast lag’ phenomenon in which, for the same dose of abrasive particles, narrower mask openings lead to channels that are shallower than wider ones. Blast lag occurs when using AJM on brittle substrates because of the natural tendency to rapidly form a V-shaped cross-sectional profile which inhibits abrasive particle strikes on the narrow vertex at the feature centerline. In this paper, the blast lag phenomenon is studied when using AJM to machine a network of microfluidic channels. It is found that, in some cases, differences in blast lag occurring at channel intersections and within the channels themselves, can lead to channel networks of nonuniform depth. A previously developed surface evolution model is adapted to allow prediction of the onset of blast lag in the channels and intersections and thus explain these differences. Finally, methods to eliminate the differences are discussed. 相似文献
86.
纳米纤维素作为一种性能优越的可再生纳米材料,应用前景极为广阔。然而,由于纳米纤维素结构上富含羟基,使其具有极强的亲水性,严重影响了纳米纤维素的疏水性能,并且在一定程度上限制了其在复合材料领域的应用。综述了纳米纤维素疏水改性的研究进展,从物理吸附、表面化学修饰(甲硅烷化、烷酰化、酯化等)、聚合物接枝共聚3个方面简述了目前应用较为广泛的疏水化改性方法,并对疏水纳米纤维素在包装材料、造纸、水净化等方面的应用现状进行了总结。最后对疏水改性纳米纤维素的未来发展进行了展望,旨在为疏水纳米纤维素的研究和应用提供参考。 相似文献
87.
Corncob liquefaction in supercritical ethanol–water was performed with and without the addition of an alkali catalyst by direct addition or biomass impregnation in a 250-cm3 batch reactor. The effects of temperature, solvent and alkali addition on the biomass conversion level and oil yield were investigated to find the optimum condition. For non-catalytic liquefaction using a 1:1 (v/v) ethanol: water ratio, a maximum oil yield and conversion level of 49.0% and 93.4%, respectively, were obtained at 340 °C. For alkali catalytic liquefaction, the oil yield with KOH addition (57.5%) was higher than that from KOH-impregnated corncob liquefaction (43.3%). The oil from liquefaction with KOH addition had higher heating value (26.7–35.3 MJ kg−1) than the corncob (19.1 MJ kg−1). The dominant components of the obtained oil were found by GC/MS analysis to be aldehyde, ester, phenol derivatives and aromatic compounds. 相似文献
88.
89.
Wei-Cheng Tang Yi-Che Su Yun-Shan Huang Ya-Tin Yu Hsin-Lung Chen I-Ming Chu 《应用聚合物科学杂志》2019,136(39):48003
While perfluoroalkyl acids (PFAAs), also known as C8s, are used extensively in textile repellent coatings, concerns have arisen for their carcinogenicity and hazardous effects on the environment. In this study, a novel water-based, nonfluoro, and nanobrush textile repelling agent was prepared by conventional sol–gel chemistry using amorphous fumed silica and n-octyltriethoxysilane as the starting materials. Minimal interaction between the designed repelling agent and marketed water-based resins was confirmed using linear viscosity region (LVR) analysis and asymmetric-flow field-flow fractionation (AF4), suggesting the self-stratification potential of the repelling agent. More specifically, the repelling agent exhibited excellent compatibility and self-stratifying ability with a force-emulsified acrylic-based resin, affording a water contact angle of 104.3° when incorporated at 7% solid content. Performance tests carried out on thermoplastic polyurethane (TPU) revealed excellent adhesion (100/100) of a final formulation, and a significant increase in water contact angle from 80.1° to 103.8° after treatment. In addition, the fouling area after the removal of a submerged sample from a mixture of slurry, polymer, and oil decreased from 48 to 1% when the repelling agent was added. Moreover, the sludge-fouling property remained unchanged after 1000 cycles of abrasion. These findings demonstrate the potential of the described nonfluoro, nanobrush repelling agent as an environmentally safe alternative for use with commercial resins, in turn realizing a fully water-based hydrophobic coating. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48003. 相似文献
90.
本文简述了酸水汽提工艺的发展概况和技术进展,详细介绍了煤化工酸水汽提装置实际运行中存在的几类主要问题,并提出切实可行的解决措施,具有一定的借鉴意义。 相似文献